The game in the southeastern Polish city of Mielec kicks off at 3:30 p.m. local time.
Poland are ranked 27th worldwide by football's governing body FIFA, while Ukraine are No. 35 in the FIFA table.
Earlier this month, Poland coach Nina Patalon named the final 23-player squad for next month’s European championships in Switzerland.
The lineup announced by Patalon includes Barcelona Femeni striker Ewa Pajor, who recently earned her 100th cap for the national team.
Women's Euro 2025, which will feature 16 teams, marks Poland’s first-ever appearance in the continental championships.
"This is a special moment for the team," Patalon said. "We will do our best to prepare for the tournament as best as we can."
Poland are scheduled to fly to Switzerland on Monday.
The Euro 2025 tournament runs from July 2 to 27.
Poland have been drawn into a group with Germany, Sweden and Denmark, and will open their campaign against Germany on July 4.
Unbeaten in their last 10 matches, Poland, captained by Pajor, recorded four wins last year and five wins and a draw so far this year.
In early June, more than 10,000 fans attended the Polish team's 3-0 home victory over Romania in the UEFA Nations League, setting what officials said was a record for women’s football attendance in Poland.
(gs)
Source: IAR, PAP, pzpn.pl